The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 25, 2014

Filed:

Jun. 16, 2009
Applicants:

Shuli Yan, Detroit, MI (US);

Steven O. Salley, Grosse Pointe Park, MI (US);

K. Y. Simon NG, West Bloomfield, MI (US);

Inventors:

Shuli Yan, Detroit, MI (US);

Steven O. Salley, Grosse Pointe Park, MI (US);

K. Y. Simon Ng, West Bloomfield, MI (US);

Assignee:

Wayne State University, Detroit, MI (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 51/00 (2006.01); C11C 1/00 (2006.01); C11C 3/00 (2006.01); B01J 23/00 (2006.01); B01J 23/10 (2006.01); B01J 23/02 (2006.01); B01J 23/44 (2006.01); B01J 37/08 (2006.01); B01J 23/06 (2006.01); B01J 35/00 (2006.01); C10L 1/02 (2006.01); B01J 37/03 (2006.01); B01J 35/02 (2006.01);
U.S. Cl.
CPC ...
B01J 23/06 (2013.01); B01J 37/08 (2013.01); C11C 3/003 (2013.01); Y02E 50/13 (2013.01); B01J 35/002 (2013.01); C10L 1/026 (2013.01); B01J 35/006 (2013.01); B01J 23/10 (2013.01); B01J 37/031 (2013.01); B01J 35/023 (2013.01);
Abstract

A method of forming a biodiesel product and a heterogeneous catalyst system used to form said product that has a high tolerance for the presence of water and free fatty acids (FFA) in the oil feedstock is disclosed. This catalyst system may simultaneously catalyze both the esterification of FAA and the transesterification of triglycerides present in the oil feedstock. The catalyst system is comprised of a mixture of zinc oxide and a second metal oxide. The zinc oxide includes a mixture of amorphous zinc oxide and zinc oxide nanocrystals, the zinc nanocrystals having a mean grain size between about 20 and 80 nanometers with at least one of the nanocrystals including a mesopore having a diameter of about 5 to 15 nanometers. Preferably, the second metal oxide is a lanthanum oxide, the lanthanum oxide being selected as one from the group of LaCO, LaOOH, and combinations or mixtures thereof.


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