The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 11, 2014

Filed:

Mar. 26, 2009
Applicants:

Andreas Rivas-nass, Schriesheim, DE;

Ralf Karch, Kleinostheim, DE;

Roland Winde, Frankfurt, DE;

Angelino Doppiu, Seligenstadt, DE;

Tina Schneider, Langenselbold, DE;

Inventors:

Andreas Rivas-Nass, Schriesheim, DE;

Ralf Karch, Kleinostheim, DE;

Roland Winde, Frankfurt, DE;

Angelino Doppiu, Seligenstadt, DE;

Tina Schneider, Langenselbold, DE;

Assignee:

Umicore AG & Co. KG, Hanau-Wolfgang, DE;

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C07F 17/02 (2006.01); B01J 31/24 (2006.01); C07C 51/36 (2006.01); C07B 53/00 (2006.01); B01J 31/18 (2006.01);
U.S. Cl.
CPC ...
C07F 17/02 (2013.01); B01J 31/2409 (2013.01); C07C 51/36 (2013.01); C07B 53/00 (2013.01); B01J 2231/645 (2013.01); B01J 2231/643 (2013.01); B01J 31/185 (2013.01); B01J 31/1865 (2013.01); B01J 2531/821 (2013.01);
Abstract

The invention relates to ruthenium complexes which have a chiral diphosphorus donor ligand and in which the ruthenium has the oxidation state (+11) and the chiral diphosphorus donor ligand has bidentate P—P coordination to the ruthenium. The ruthenium complexes are present in two forms (cationic type A and uncharged type B), are cyclic and have a four- to six-membered ring incorporating the diphosphorus donor ligand. The chiral diphosphorus donor ligands are selected from the group consisting of diphosphines, diphospholanes, diphosphites, diphosphonites and diazaphospholanes. Furthermore, processes for preparing the ruthenium complexes of types A and B, which are based on ligand exchange reactions, are described. The Ru complexes are used as catalysts for homogeneous asymmetric catalysis for preparing organic compounds.


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