The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 11, 2014

Filed:

Nov. 25, 2009
Applicants:

Michael S. Freund, Winnipeg, CA;

Bhavana A. Deore, Ottawa, CA;

Inventors:

Michael S. Freund, Winnipeg, CA;

Bhavana A. Deore, Ottawa, CA;

Assignee:

University of Manitoba, Winnipeg, Manitoba, CA;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
H01B 1/00 (2006.01); B32B 5/16 (2006.01); C08L 81/00 (2006.01); C08L 85/00 (2006.01); C08G 79/08 (2006.01); C09D 5/08 (2006.01); C08G 73/02 (2006.01); C09D 5/24 (2006.01); C09D 179/02 (2006.01);
U.S. Cl.
CPC ...
C09D 5/08 (2013.01); C08G 73/0266 (2013.01); C09D 5/24 (2013.01); C09D 179/02 (2013.01); Y10S 977/773 (2013.01); Y10S 977/832 (2013.01); Y10S 977/902 (2013.01);
Abstract

Poly(anilineboronic acid)/phosphate nanoparticle dispersions are produced in high yields using the reactivity of the boronic acid moiety with phosphate in the presence of fluoride. The poly(anilineboronic acid)/phosphate dispersions have been characterized using spectroscopic, microscopic and electrochemical techniques. According toB NMR studies, the formation of anionic tetrahedral boronate group in phosphoric acid in the presence of fluoride forms the basis of self-doped, stabilized PABA nanoparticle dispersion. Transmission electron microscope images show that 25-50 nm diameter PABA nanoparticles are formed under these conditions. UV-vis, FT-IR-ATR spectroscopic and cyclic voltammetric results confirm the formation of the conducting form of PABA. Films produced from these particles exhibit enhanced redox stability and potential dependant conductivity under neutral and basic pH conditions due to the formation of a boron-phosphate complex containing fluoride, which results in a self-doped form of the polymer.


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