The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 04, 2014

Filed:

Apr. 26, 2006
Applicants:

Robert A. Dagle, Richland, WA (US);

Yong Wang, Richland, WA (US);

Guanguang Xia, Pasco, WA (US);

Inventors:

Robert A. Dagle, Richland, WA (US);

Yong Wang, Richland, WA (US);

Guanguang Xia, Pasco, WA (US);

Assignee:

Battelle Memorial Institute, Richland, WA (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
B01J 23/00 (2006.01); B01J 23/02 (2006.01); B01J 23/08 (2006.01); B01J 23/40 (2006.01); B01J 23/42 (2006.01); B01J 23/56 (2006.01); B01J 21/04 (2006.01); B01J 20/00 (2006.01); C01B 3/58 (2006.01); B01J 35/00 (2006.01); B01J 23/46 (2006.01); B01J 35/10 (2006.01);
U.S. Cl.
CPC ...
C01B 3/586 (2013.01); B01J 2219/00781 (2013.01); C01B 2203/047 (2013.01); B01J 21/04 (2013.01); B01J 35/1019 (2013.01); B01J 35/002 (2013.01); B01J 23/462 (2013.01); C01B 2203/0445 (2013.01); B01J 35/006 (2013.01);
Abstract

Carbon monoxide (CO) is selectively reacted with hydrogen (H) over a ruthenium (Ru) on alumina catalyst at a temperature of about 210 to about 290° C. To be a viable option for micro catalytic fuel processing devices, highly active, selective, and stable catalysts must be demonstrated with as large a temperature window for feasible operation as possible. We have studied the effects of metal loading, preparation method, pretreatment conditions, and choice of support on the performance of Ru-based catalysts for such applications. Catalyst testing results and catalyst characterization using XRD and BET are discussed. In one example, operating at a gas hourly space velocity (GHSV) of 13,500 hr, a 3% Ru/AlOcatalyst yielded CO outputs less than 100 ppm in a temperature range from 240° C. to 285° C., while not exceeding a hydrogen consumption of 10%. This catalyst was further successfully demonstrated in a microchannel device.


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