The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 21, 2014

Filed:

Oct. 05, 2011
Applicants:

Naritoshi Yoshimura, Funabashi, JP;

Shinji Kiyono, Kimitsu, JP;

Tetsuya Hamada, Ichihara, JP;

Eiji Watanabe, Chiba, JP;

Saiko Sawada, Chiba, JP;

Inventors:

Naritoshi Yoshimura, Funabashi, JP;

Shinji Kiyono, Kimitsu, JP;

Tetsuya Hamada, Ichihara, JP;

Eiji Watanabe, Chiba, JP;

Saiko Sawada, Chiba, JP;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 209/00 (2006.01); C07C 253/34 (2006.01); C07C 209/48 (2006.01); C07C 253/22 (2006.01); B01J 23/44 (2006.01); B01J 25/00 (2006.01); B01J 25/02 (2006.01);
U.S. Cl.
CPC ...
C07C 209/48 (2013.01); C07B 2200/09 (2013.01); B01J 23/44 (2013.01); B01J 25/00 (2013.01); B01J 25/02 (2013.01); C07C 253/34 (2013.01); C07C 2101/14 (2013.01); C07C 253/22 (2013.01);
Abstract

A method for producing trans-1,4-bis(aminomethyl)cyclohexane includes a nuclear hydrogenation step of producing a hydrogenated terephthalic acid or terephthalic acid derivative by nuclear hydrogenation of a terephthalic acid or terephthalic acid derivative, the terephthalic acid or terephthalic acid derivative being at least one selected from the group consisting of terephthalic acid, terephthalic acid ester, and terephthalic acid amide; a cyanation step of treating the hydrogenated terephthalic acid or terephthalic acid derivative with ammonia, thereby producing 1,4-dicyanocyclohexane, and producing trans-1,4-dicyanocyclohexane from the obtained 1,4-dicyanocyclohexane; and an aminomethylation step of treating the trans-1,4-dicyanocyclohexane with hydrogen, thereby producing trans-1,4-bis(aminomethyl)cyclohexane. Metal oxide is used as a catalyst in the cyanation step, and the obtained trans-1,4-dicyanocyclohexane has a metal content of 3000 ppm or less.


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