The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 14, 2014

Filed:

Dec. 22, 2011
Applicants:

Dimitris Katsoulis, Midland, MI (US);

Robert Thomas Larsen, Midland, MI (US);

Inventors:

Dimitris Katsoulis, Midland, MI (US);

Robert Thomas Larsen, Midland, MI (US);

Assignee:

Dow Corning Corporation, Midland, MI (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08G 77/06 (2006.01); C08L 83/04 (2006.01); C08G 77/08 (2006.01); C07F 7/21 (2006.01); C08G 77/04 (2006.01);
U.S. Cl.
CPC ...
C08L 83/04 (2013.01); C08G 77/08 (2013.01); C07F 7/21 (2013.01); C08L 2666/14 (2013.01); C08G 77/045 (2013.01);
Abstract

A mixture of at least two polyhedral oligomeric silsesquioxane (POSS) compounds is formed in the presence of rhenium on cerium(IV) oxide. The POSS compounds are formed utilizing a method that includes the step of combining (a) a trihalosilane, (b) hydrogen gas, and (c) the rhenium on cerium(IV) oxide, in a reactor at a temperature of from 250° C. to 600° C. to form the mixture. The trihalosilane has the formula RSiXwherein R is an alkyl group having from 1 to 4 carbon atoms, an aryl group, and wherein X is a halo atom. This method allows for the efficient, predictable, and accurate production of the POSS compounds with a minimized need for use of expensive separation techniques. In addition, this method produces the POSS compounds in commercially useful quantities as major reaction products thereby avoiding the need to run multiple reactions.


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