The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 07, 2014

Filed:

Nov. 20, 2012
Applicant:

Celanese International Corporation, Irving, TX (US);

Inventors:

Victor J. Johnston, Houston, TX (US);

David Lee, Seabrook, TX (US);

Adam Orosco, Houston, TX (US);

R. Jay Warner, Houston, TX (US);

Heiko Weiner, Pasadena, TX (US);

Radmila Wollrab, Pasadena, TX (US);

Zhenhua Zhou, Houston, TX (US);

Emily Duff, League City, TX (US);

Iva Franjkic, League City, TX (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 29/149 (2006.01); C07C 67/08 (2006.01); C07C 29/00 (2006.01); B01J 23/62 (2006.01); B01J 23/78 (2006.01); B01J 23/86 (2006.01); B01J 23/652 (2006.01); B01J 37/02 (2006.01); B01J 23/89 (2006.01); B01J 23/80 (2006.01); B01J 23/656 (2006.01); B01J 23/60 (2006.01); B01J 23/40 (2006.01); B01J 21/18 (2006.01); B01J 23/889 (2006.01);
U.S. Cl.
CPC ...
C07C 29/00 (2013.01); B01J 23/626 (2013.01); B01J 23/78 (2013.01); B01J 23/868 (2013.01); B01J 23/6525 (2013.01); B01J 37/0201 (2013.01); C07C 67/08 (2013.01); B01J 23/624 (2013.01); B01J 23/8913 (2013.01); C07C 29/149 (2013.01); B01J 23/80 (2013.01); B01J 23/628 (2013.01); B01J 23/6567 (2013.01); B01J 23/60 (2013.01); B01J 23/6527 (2013.01); B01J 23/40 (2013.01); B01J 21/18 (2013.01); B01J 23/8892 (2013.01);
Abstract

Disclosed herein are processes for alcohol production by hydrogenating acetic acid to obtain a mixture of ethanol and acetic acid, esterifying the mixture to produce an esterification product and reducing the esterification product. The mixture may provide a sufficient amount of ethanol and acetic acid for esterification and reduces the need for additional acetic acid and/or ethanol. This may reduce the recycle of ethanol in the hydrogenolysis process and improve ethanol productivity.


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