The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 07, 2014

Filed:

Aug. 19, 2011
Applicants:

James H. Zink, League City, TX (US);

Mark O. Scates, Houston, TX (US);

Ronald D. Shaver, Houston, TX (US);

G. Paull Torrence, League City, TX (US);

Inventors:

James H. Zink, League City, TX (US);

Mark O. Scates, Houston, TX (US);

Ronald D. Shaver, Houston, TX (US);

G. Paull Torrence, League City, TX (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 29/149 (2006.01); C07C 51/12 (2006.01); C01B 3/50 (2006.01); C07C 1/04 (2006.01);
U.S. Cl.
CPC ...
C01B 3/501 (2013.01); C07C 51/12 (2013.01); C07C 29/149 (2013.01); C01B 2203/0445 (2013.01); C01B 2203/0405 (2013.01); C07C 1/04 (2013.01); C01B 2203/043 (2013.01); C01B 2203/047 (2013.01); C01B 2203/046 (2013.01); C01B 2203/0415 (2013.01);
Abstract

Processes and systems for forming ethanol from methanol. The process involves carbonylating the methanol to form acetic acid and hydrogenating the acetic acid to form ethanol. In a first aspect, at least some hydrogen for the hydrogenating step is derived from a tail gas stream formed in the carbonylation step. In a second aspect, at least some carbon monoxide for the carbonylation step is derived from a vapor stream in the hydrogenation system. In a third aspect, a syngas stream is separated to form a hydrogen stream and a carbon monoxide stream, and the hydrogen stream is methanated to remove residual carbon monoxide prior to being introduced into the hydrogenation system.


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