The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 07, 2014

Filed:

Oct. 11, 2011
Applicants:

Kazuaki Ishihara, Nagoya, JP;

Muhammet Uyanik, Nagoya, JP;

Inventors:

Kazuaki Ishihara, Nagoya, JP;

Muhammet Uyanik, Nagoya, JP;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07D 313/16 (2006.01); C07B 33/00 (2006.01); C07D 307/83 (2006.01); C07D 309/30 (2006.01); C07D 313/04 (2006.01); C07D 307/935 (2006.01); C07D 323/04 (2006.01); C07D 307/33 (2006.01); C07D 307/77 (2006.01); C07D 307/88 (2006.01); C07D 307/79 (2006.01);
U.S. Cl.
CPC ...
C07D 313/04 (2013.01); C07B 33/00 (2013.01); C07D 307/83 (2013.01); C07D 309/30 (2013.01); C07D 307/935 (2013.01); C07D 323/04 (2013.01); C07D 307/33 (2013.01); C07D 307/77 (2013.01); C07D 307/88 (2013.01); C07D 307/79 (2013.01);
Abstract

The present invention relates to a method for manufacturing an ester from a ketone or an aldehyde, which is a reactive substrate, by a Baeyer-Villiger oxidation reaction using hydrogen peroxide, and in this method, as a catalyst, M(BAr), which is a metal borate, is used (M represents an alkali metal or an alkaline earth metal; Ar represents an aryl; and n is the same number as the valence of M). For example, when cyclohexanone was used as the reactive substrate, and Sr[B(3,5-CFCH)]was used as the catalyst, ε-caprolactone was obtained at an isolated yield of 82%.


Find Patent Forward Citations

Loading…