The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 30, 2014

Filed:

Apr. 25, 2013
Applicant:

E I Du Pont DE Nemours and Company, Wilmington, DE (US);

Inventors:

Alan Martin Allgeier, Wilmington, DE (US);

Wathudura Indika Namal De Silva, Rahway, NJ (US);

Carl Andrew Menning, Newark, DE (US);

Joachim C Ritter, Wilmington, DE (US);

Sourav Kumar Sengupta, Wilmington, DE (US);

Assignee:

E I du Pont de Nemours and Company, Wilmington, DE (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 27/04 (2006.01); C07C 29/132 (2006.01); C07C 209/16 (2006.01); C07D 309/06 (2006.01); B01J 27/188 (2006.01); B01J 23/888 (2006.01); C07C 29/60 (2006.01);
U.S. Cl.
CPC ...
C07C 29/60 (2013.01); B01J 27/188 (2013.01); B01J 23/888 (2013.01); C07C 209/16 (2013.01);
Abstract

Disclosed herein are processes for preparing an α,ω-C-diol, wherein n is 5 or greater, from a feedstock comprising a Coxygenate. In one embodiment, the process comprises contacting the feedstock with hydrogen gas in the presence of a catalyst comprising a first metal component comprising Ni, Ir, Pt, Rh, Ru, Pd, Fe, Ag, or Au; a heteropoly acid component comprising H[P(WO)], H[Si(WO)], H[P(MoO)], H[Si(MoO)], CsH[P(WO)]CsH[Si(WO)], or mixtures thereof; optionally a second metal component comprising Cr, a Cr oxide, Ni, a Ni oxide, Fe, a Fe oxide, Co, a Co oxide, Mn, a Mn oxide, Mo, a Mo oxide, W, a W oxide, Re, a Re oxide, Zn, a Zn oxide, SiO, or AlO; optionally at least one promoter comprising Na, K, Mg, Rb, Cs, Ca, Sr, Ba, Ce, or mixtures thereof; and optionally a support. In one embodiment, the optional support is present in the catalyst and comprises WO, SiO, AlO, carbon, TiO, ZrO, SiO—AlO, montmorillonite, SiO—TiO, tungstated ZrO, zeolites, VO, MoO, or mixtures thereof. The Coxygenate may be obtained from a biorenewable resource.


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