The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 30, 2014

Filed:

Oct. 06, 2011
Applicants:

Christian Sidot, Compiegne, FR;

Audrey Caron, Compiegne, FR;

Miriam Ladwig, Diezenbach, DE;

Gerd Reinhardt, Kelkheim, DE;

Inventors:

Christian Sidot, Compiegne, FR;

Audrey Caron, Compiegne, FR;

Miriam Ladwig, Diezenbach, DE;

Gerd Reinhardt, Kelkheim, DE;

Assignee:
Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07F 15/02 (2006.01); C07F 13/00 (2006.01);
U.S. Cl.
CPC ...
C07F 15/02 (2013.01); C07F 13/005 (2013.01); C07F 13/00 (2013.01); C07F 15/025 (2013.01);
Abstract

The invention relates to a method for producing metal complexes of formula (2) [MLX]Y(2), where M is a metal from the group consisting of Mn(II), Mn(III), Mn(IV), Fe(II), Fe(III) or Fe(IV), X is a coordinating compound selected from mono-, bi- or tri-charged anions or neutral molecules which can coordinate to a metal in mono-, bi- or tri-dentate form, Y represents a non-coordinating counter-ion which ensures charge equalization of the complex, L represents a ligand of formula (1) or the protonized or de-protonized form thereof, and a, x, n, m, R, R, R, Rand z have the meanings described in claim. Said method is characterized in that the reaction of one or more ligands of formula (1) with an iron salt or manganese salt is carried out in an acetone/water mixture in a temperature range from 0 to 50° C. and for this purpose a solution or a suspension of the one or more ligands of formula (1) in acetone is brought in contact with an aqueous metal salt solution of the iron salt or manganese salt in the temperature range in which the reaction takes place.


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