The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 02, 2014

Filed:

Mar. 17, 2010
Applicants:

Craig L Hill, Atlanta, GA (US);

Yurii V Gueletii, Decatur, GA (US);

Djamaladdin G. Musaev, Atlanta, GA (US);

Qiushi Yin, Tucker, GA (US);

Bogdan Botar, Juelich, DE;

Inventors:

Craig L Hill, Atlanta, GA (US);

Yurii V Gueletii, Decatur, GA (US);

Djamaladdin G. Musaev, Atlanta, GA (US);

Qiushi Yin, Tucker, GA (US);

Bogdan Botar, Juelich, DE;

Assignee:

Emory University, Atlanta, GA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 27/188 (2006.01); B01J 35/00 (2006.01); B01J 23/00 (2006.01); B01J 23/652 (2006.01); C01B 3/04 (2006.01); C01B 13/02 (2006.01); C01G 51/00 (2006.01); C01G 55/00 (2006.01); H01M 8/06 (2006.01); B01J 27/199 (2006.01);
U.S. Cl.
CPC ...
B01J 35/0033 (2013.01); B01J 27/199 (2013.01); B01J 23/002 (2013.01); B01J 23/6527 (2013.01); B01J 27/188 (2013.01); B01J 2523/00 (2013.01); C01B 3/042 (2013.01); C01B 13/0207 (2013.01); C01G 51/006 (2013.01); C01G 55/002 (2013.01); C01P 2002/82 (2013.01); C01P 2002/84 (2013.01); C01P 2002/86 (2013.01); C01P 2002/88 (2013.01); C01P 2006/40 (2013.01); H01M 8/0606 (2013.01); Y02E 60/364 (2013.01); Y02E 60/50 (2013.01);
Abstract

Homogeneous water oxidation catalysts (WOCs) for the oxidation of water to produce hydrogen ions and oxygen, and methods of making and using thereof are described herein. In a preferred embodiment, the WOC is a polyoxometalate WOC which is hydrolytically stable, oxidatively stable, and thermally stable. The WOC oxidized waters in the presence of an oxidant. The oxidant can be generated photochemically, using light, such as sunlight, or electrochemically using a positively biased electrode. The hydrogen ions are subsequently reduced to form hydrogen gas, for example, using a hydrogen evolution catalyst (HEC). The hydrogen gas can be used as a fuel in combustion reactions and/or in hydrogen fuel cells. The catalysts described herein exhibit higher turn over numbers, faster turn over frequencies, and/or higher oxygen yields than prior art catalysts.


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