The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.
The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.
Patent No.:
Date of Patent:
Aug. 26, 2014
Filed:
May. 15, 2013
Arindam Mazumdar, Stow, OH (US);
Frank James Feher, Copley, OH (US);
Arindam Mazumdar, Stow, OH (US);
Frank James Feher, Copley, OH (US);
The Goodyear Tire & Rubber Company, Akron, OH (US);
Abstract
The present invention is directed to a method of making a functionalized elastomer, comprising the steps of polymerizing at least one diene monomer and optionally a vinyl aromatic monomer in the presence of an initiator of formula (II) to produce a protected hydroxyl end-terminated polymer where R, R, Rcan all be the same or different and are selected from the group consisting of alkyls having from 1 to 8 carbon atoms, cycloalkyls having from 3 to 11 carbon atoms, or aryls having from 6 to 14 carbon atoms, Ris an alkylene having from 1 to 8 carbon atoms, a cycloalkylene having from 3 to 11 carbon atoms, or an arylene having from 6 to 14 carbon atoms, X is S, O or NH, and Li is lithium; de-protecting the protected hydroxyl end-terminated elastomer to produce a hydroxyl end-functionalized polymer; reacting the hydroxyl end-funtionalized polymer with a maleimido acid chloride to produce a maleimido end-functionalized polymer; and reacting the maleimido end-functionalized polymer with a thiol-terminated polymer derived from a monomer having a hydrogen bond donor site and a hydrogen bond acceptor site to produce the functionalized elastomer.