The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 01, 2014

Filed:

Jun. 14, 2011
Applicants:

Pascal Mertens, Heverlee, BE;

Dirk DE Vos, Holsbeek, BE;

Bart Steenackers, Kasterlee, BE;

Inventors:

Pascal Mertens, Heverlee, BE;

Dirk De Vos, Holsbeek, BE;

Bart Steenackers, Kasterlee, BE;

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C07C 45/66 (2006.01);
U.S. Cl.
CPC ...
Abstract

The invention relates to a process for the production of hexahydro-iso-alpha-acids starting from iso-alpha-acids (or tetrahydro-iso-alpha-acids) in which iso-alpha-acids (or tetrahydro-iso-alpha-acids) are mixed with a heterogeneous ruthenium containing catalyst, that catalyzes the hydrogenation from iso-alpha-acids or tetrahydro-iso-alpha-acids to hexahydro-iso-alpha-acids, either in solvent-free conditions, or in the presence of a solvent phase (e.g. carbon dioxide, water, ethanol or another organic solvent, or mixtures thereof), and in the absence or presence of other hop compounds (such as beta-acids). The resulting mixture is then subjected to a temperature at which the iso-alpha-acid (or tetrahydro-iso-alpha-acid) containing reaction medium is sufficiently low in viscosity to allow easy mixing with the heterogeneous ruthenium containing catalyst and held under a hydrogen containing atmosphere (either pure hydrogen gas or mixed with an inert gas) for a reaction time sufficient to effect high conversion of the iso-alpha-acid (or tetrahydro-iso-alpha-acid) reactant into the hexahydro-iso-alpha-acid product.


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