The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 17, 2014

Filed:

Mar. 15, 2012
Applicants:

Scott A. Scholten, Katy, TX (US);

Joe D. Allison, Bartlesville, OK (US);

Brian C. Dunn, Bartlesville, OK (US);

Inventors:

Scott A. Scholten, Katy, TX (US);

Joe D. Allison, Bartlesville, OK (US);

Brian C. Dunn, Bartlesville, OK (US);

Assignee:

Phillips 66 Company, Houston, TX (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 27/00 (2006.01); C07C 9/04 (2006.01); C07C 1/12 (2006.01);
U.S. Cl.
CPC ...
C07C 9/04 (2013.01); C07C 1/12 (2013.01); C07C 2523/26 (2013.01); C07C 2523/755 (2013.01);
Abstract

Enhanced mixed metal catalysts are provided which allow high conversions of carbon dioxide to methane, in some cases up to about 100% conversion. Methods of preparing enhanced mixed metal catalysts comprise a series of steps involving combining nickel and chromium salts with a nucleation promoter in a base environment to form a gel, allowing the gel to digest to form a solid and a mother liquor, isolating the solid, washing the solid, drying the solid, and thermally treating the solid to form a nickel-chromium catalyst. Methanation processes using the catalysts are also provided. The enhanced mixed metal catalysts provide more efficient conversion and lower operating temperatures for carbon dioxide methanation when compared to conventional methanation catalysts. Additionally, these enhanced catalyst formulations allow realization of higher value product from captured carbon dioxide.


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