The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 29, 2014

Filed:

May. 31, 2012
Applicants:

David William Norman, Kingsport, TN (US);

Joost Nicolaas Hendrik Reek, Amsterdam, NL;

Tatiana Renee Marie-louise Besset, Amsterdam, NL;

Inventors:

David William Norman, Kingsport, TN (US);

Joost Nicolaas Hendrik Reek, Amsterdam, NL;

Tatiana Renee Marie-Louise Besset, Amsterdam, NL;

Assignee:

Eastman Chemical Company, Kingsport, TN (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 45/50 (2006.01); B01J 31/24 (2006.01);
U.S. Cl.
CPC ...
Abstract

Modification of a unique supramolecular assembly of a pyridylphosphine ligand and a metal centered porphyrin complex is shown to give unprecedented selectivities to branched aldehydes via rhodium catalyzed hydroformylation of propylene and 1-octene. Use of magnesium in the porphyrin center provides the highest reported concentrations of iso-butyraldehyde and 2-methyl-octanal.


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