The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 01, 2014

Filed:

Nov. 09, 2011
Applicants:

Mark O. Scates, Houston, TX (US);

Ronald D. Shaver, Houston, TX (US);

James H. Zink, League City, TX (US);

Raymond J. Zinobile, Houston, TX (US);

Inventors:

Mark O. Scates, Houston, TX (US);

Ronald D. Shaver, Houston, TX (US);

James H. Zink, League City, TX (US);

Raymond J. Zinobile, Houston, TX (US);

Assignee:
Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 27/04 (2006.01);
U.S. Cl.
CPC ...
Abstract

In one embodiment, the invention is to a process for producing ethanol, comprising the step of reacting carbon monoxide with at least one reactant in a reactor containing a reaction medium to produce a liquid reaction product comprising acetic acid. The process further comprises the step of separating the reaction product in a flasher into a liquid recycle stream and a vapor stream. The vapor stream is then distilled in a rectification tower and an overhead stream and an acetic acid stream are withdrawn therefrom, wherein the acetic acid is substantially free of halogen promoters. The process further comprises the step of hydrogenating acetic acid of the acetic acid stream in the presence of a second catalyst and under conditions effective to form a crude ethanol product comprising ethanol and water. Ethanol is recovered from the crude ethanol product.


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