The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 04, 2014

Filed:

Nov. 04, 2008
Applicants:

Ruth A. Davis, Allentown, PA (US);

Norman Macleod, Hartlepool, GB;

Gordon Edward Wilson, Stockton-on-Tees, GB;

Inventors:

Ruth A. Davis, Allentown, PA (US);

Norman Macleod, Hartlepool, GB;

Gordon Edward Wilson, Stockton-on-Tees, GB;

Assignees:

Air Products and Chemicals, Inc., Allentown, PA (US);

Johnson Matthey PLC, London, GB;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 5/02 (2006.01);
U.S. Cl.
CPC ...
Abstract

A process for hydrogenating olefins is disclosed. The olefins are present in a feed gas which includes Hand one or more sulfur compounds. The sulfur compounds may include HS and organic sulfur compounds. The feed gas is passed through a reactor at an inlet temperature from 100° C. to 250° C. The reactor contains a catalyst which is active at the inlet temperature. The reactor may be adiabatic. Saturated hydrocarbons are formed from the olefins. A temperature gradient may be formed in the reactor due to the exothermic nature of the hydrogenation reaction, causing the temperature to increase downstream in the reactor. At temperatures higher than the inlet temperature, HS may be formed from organic sulfur compounds. A gas mixture including saturated hydrocarbons, HS and Hexits the reactor and may be brought into contact with a chemical adsorbent which removes the HS. The gas stream may then be passed to a steam methane reformer.


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