The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 11, 2014

Filed:

Oct. 06, 2010
Applicants:

Lawrence M. Woods, Littleton, CO (US);

Joseph H. Armstrong, Littleton, CO (US);

Richard Thomas Tregfio, Thornton, CO (US);

John L. Harrington, Colorado Springs, CO (US);

Inventors:

Lawrence M. Woods, Littleton, CO (US);

Joseph H. Armstrong, Littleton, CO (US);

Richard Thomas Tregfio, Thornton, CO (US);

John L. Harrington, Colorado Springs, CO (US);

Assignee:

Ascent Solar Technologies, Inc., Thornton, CO (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
H01L 25/18 (2006.01); H01L 31/0264 (2006.01); H01L 31/0272 (2006.01); H02N 6/00 (2006.01);
U.S. Cl.
CPC ...
Abstract

A method of manufacture of I-III-VI-absorber photovoltaic cells involves sequential deposition of films comprising one or more of silver and copper, with one or more of aluminum indium and gallium, and one or more of sulfur, selenium, and tellurium, as compounds in multiple thin sublayers to form a composite absorber layer. In an embodiment, the method is adapted to roll-to-roll processing of photovoltaic cells. In an embodiment, the method is adapted to preparation of a CIGS absorber layer having graded composition through the layer of substitutions such as tellurium near the base contact and silver near the heterojunction partner layer, or through gradations in indium and gallium content. In a particular embodiment, the graded composition is enriched in gallium at a base of the layer, and silver at the top of the layer. In an embodiment, each sublayer is deposited by co-evaporation of copper, indium, gallium, and selenium, which react in-situ to form CIGS.


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