The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 21, 2014

Filed:

Oct. 25, 2012
Applicant:

Shell Oil Company, Houston, TX (US);

Inventors:

Justus Theodorus Gerardus Te Braake, Amsterdam, NL;

Maarten Bracht, Amsterdam, NL;

Desmond Andrew Bungku, Amsterdam, NL;

Wouter David Van De Graaf, Amsterdam, NL;

Xander Linders, Amsterdam, NL;

Sivakumar Sadasivan Vijayakumari, Amsterdam, NL;

Assignee:

Shell Oil Company, Houston, TX (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C01B 3/50 (2006.01);
U.S. Cl.
CPC ...
Abstract

A method for producing a gas comprising at least 80 vol % carbon monoxide from a Fischer-Tropsch off-gas comprising: (1) feeding Fischer-Tropsch off-gas through a column comprising an adsorbent bed at high pressure and discharging effluent; (2) reducing the pressure in the column and the bed slightly; (3) rinsing the column and the adsorbent bed with methane or carbon dioxide; (4) rinsing the column and the adsorbent bed with carbon dioxide; (5) reducing the pressure of the column and adsorbent bed to a low pressure; (6) rinsing the column and adsorbent bed with a mixture of hydrogen and nitrogen; (7) pressurizing the column and adsorbent bed to a high pressure using a mixture of hydrogen and nitrogen. The carbon monoxide rich product stream obtained in step (3) can be sent as feed to a Fischer-Tropsch reaction. In an embodiment, a gas comprising at least 80 vol % hydrogen is also produced.


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