The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 24, 2013

Filed:

Jan. 21, 2013
Applicant:

King Fahd University of Petroleum and Minerals, Dhahran, SA;

Inventors:

Mamdouh Ahmad Al-Harthi, Dhahran, SA;

Omer Yahya Bakather, Dhahran, SA;

Sadhan Kumar De, Dhahran, SA;

Reyad Awwad Khalaf Shawabkeh, Dhahran, SA;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 4/18 (2006.01); C08F 2/06 (2006.01); C08F 110/02 (2006.01); C08F 4/685 (2006.01);
U.S. Cl.
CPC ...
Abstract

The method of making high-density polyethylene with titania-iron nanofillers involves mixing a TiO/Fe titania-iron nanofiller with a vanadium (III) complex bearing salicylaldiminato ligands polymerization catalyst in a reactor. The reactor is then charged with toluene and heated to a temperature of about 30° C. Following heating, ethylene is fed into the reactor at a fixed pressure, and a methyl aluminum dichloride cocatalyst is added to initiate in situ polymerization. Polymerization is quenched to yield high-density polyethylene with titania-iron nanofillers, which is then washed and dried. Through the addition of a TiO/Fe nanofiller, the molecular weight, the crystallinity and the melting temperature of high-density polyethylene are all increased, while the polydispersity index (PDI) is decreased.


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