The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 30, 2013

Filed:

Apr. 17, 2009
Applicants:

Marek A. Osinski, Albuquerque, NM (US);

Nathan J. Withers, Albuquerque, NM (US);

Brian A. Akins, Edgewood, NM (US);

Gennady A. Smolyakov, Albuquerque, NM (US);

Krishnaprasad Sankar, Albuquerque, NM (US);

Inventors:

Marek A. Osinski, Albuquerque, NM (US);

Nathan J. Withers, Albuquerque, NM (US);

Brian A. Akins, Edgewood, NM (US);

Gennady A. Smolyakov, Albuquerque, NM (US);

Krishnaprasad Sankar, Albuquerque, NM (US);

Assignee:

STC.UNM, Albuquerque, NM (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C09K 11/08 (2006.01); C09K 11/61 (2006.01);
U.S. Cl.
CPC ...
Abstract

Scintillator material comprising nanoparticles (nanocrystals) comprising lead (Pb), iodine (I), and optionally one or both of oxygen (O) and hydrogen (H) wherein the nanoparticles exhibit room-temperature scintillation under gamma irradiation. The scintillator nanoparticles can comprise PbOI. The scintillator nanoparticles can comprise PbIOH in generally equiatomic proportions or non-equiatomic variants thereof that exhibit scintillation under gamma irradiation. The scintillator nanoparticles have a particle dimension in the range of about 5 to about 100 nm. Microparticles (microcrystals) also are provided comprising lead (Pb), iodine (I), and optionally one or both of oxygen (O) and hydrogen (H) grown in a nanoparticle colloidal solution over time to a particle dimension greater than 0.1 μm, such as about 2 microns. A heterogeneous scintillator material is provided comprising core/shell nanoparticles having a highly hygroscopic or deliquescent halide-based core activated with trivalent Lnor divalent Lnlanthanide ions (Ln=La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) and a stable non-hygroscopic shell thereon. The heterogeneous nanoparticles can comprise highly hygroscopic lanthanide halide (LaBr, LuI) cores protected with stable non-hygroscopic LaFshells. The heterogeneous nanoparticles can comprise deliquescent alkaline earth halide (SrI, BaI) cores protected with stable non-hygroscopic (SrF, BaF) shells.


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