The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 06, 2012

Filed:

Nov. 05, 2004
Applicants:

Bonnie Gary Mckinnie, Magnolia, AR (US);

Joseph H. Miller, Baton Rouge, LA (US);

Inventors:

Bonnie Gary McKinnie, Magnolia, AR (US);

Joseph H. Miller, Baton Rouge, LA (US);

Assignee:

Albermarle Corporation, Baton Rouge, LA (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C11D 17/00 (2006.01);
U.S. Cl.
CPC ...
Abstract

Certain substituted phenolic compounds when used with or without 1,2-epoxides as the sole stabilizer components are very effective in stabilizing n-propyl bromide (NPB). In a standard commercially important 60° C. stability test, representative substituted phenolic compounds used pursuant to this invention, can enable NPB to pass the test even though present at levels of about 50 ppm (wt/wt) or less in NPB containing no other stabilizer additive component. In fact, amounts as low as 1 ppm have been found effective with various substituted phenolic compounds. In addition, it has been found that one of the preferred stabilizers of this invention—2,6-di-tert-butyl-p-cresol—even though higher boiling than NPB, left inconsequential amounts of residue at least throughout the range of 1 to 30 ppm (wt/wt). Also, it has been found that certain other preferred stabilizers of this invention can provide synergistically improved stability in passing the 60° C. stability test when used with at least one 1,2-epoxide, notably butylene oxide.


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