Supported metallocene catalyst, method of preparing the catalyst and method of preparing polyolefin using the catalyst

Abstract

Provided are a supported metallocene catalyst which has excellent supporting efficiency due to an interaction between a cocatalyst supported on a carrier and a metallocene compound substituted with a functional group that can function as a Lewis base, such as acetal, ketal, tert-alkoxy alkyl, benzyloxy alkyl, substituted benzyloxy alkyl, monothioacetal, or monothioketal, and a method of polymerizing an olefin using the supported metallocene catalyst. In the supported metallocene catalyst, the metallocene catalyst is strongly bound to the carrier due to a Lewis acid-base interaction between the metallocene compound and the cocatalyst, and thus the metallocene catalyst is not separated from the carrier during the polymerization of polyolefin in a slurry or gas phase method. Thus, fouling is prevented and the prepared polymer has a good particle shape and a high apparent density. Thus, the supported metallocene catalyst can be suitably used in a conventional slurry or gas phase polymerization process.