The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 17, 2012

Filed:

Oct. 18, 2007
Applicants:

Ivan Exnar, Itingen, CH;

Shaik Mohammed Zakeeruddin, Renens, CH;

Michael Gratzel, St-Sulpice, CH;

Ladislav Kavan, Praha, CZ;

Inventors:

Ivan Exnar, Itingen, CH;

Shaik Mohammed Zakeeruddin, Renens, CH;

Michael Gratzel, St-Sulpice, CH;

Ladislav Kavan, Praha, CZ;

Assignee:

Dow Global Technologies LLC, Midland, MI (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
H01M 4/60 (2006.01); H01M 4/13 (2006.01); D01F 9/12 (2006.01);
U.S. Cl.
CPC ...
Abstract

This invention concerns a novel method for surface derivatization of electrode materials for Li-ion batteries. The derivatization is based on adsorption of a composite assembly consisting of amphiphilic redox active molecule attached to single walled carbon nanotube (SWCNT). Its role consists in the enhancement of electronic conductivity of electrode materials, such as phosphate olivines, without requesting any significant increase of the electrode volume and mass. The SWCNT is linked to the redox molecule via non-covalent or covalent interaction with the hydrophobic part of the molecule or electrostatic interaction. The hydrophilic part of the molecule serves as the anchoring site for surface modification of the electrode active material. The redox potential of the molecule is close to the redox potential of the electrode active material. The adsorbed assembly of redox-molecule & SWCNT thus improves the charge transfer from a current collector to the electrode active material.


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