The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.
The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.
Patent No.:
Date of Patent:
May. 24, 2011
Filed:
Oct. 28, 2004
Mario Pagliaro, Palermo, IT;
Rosaria Ciriminna, Palermo, IT;
Mario Pagliaro, Palermo, IT;
Rosaria Ciriminna, Palermo, IT;
Consiglio Nazionale Delle Ricerche, Rome, IT;
Abstract
Nanohybrid sol-gel materials, based on silica organically modified (ormosil) and doped with the ruthenium species tetra-n-propylammonium perruthenate (TPAP) are highly efficient catalysts for the selective oxidation of alcohols to carbonyls with oxygen at low pressure, in organic solvents as well as in carbon dioxide in supercritical state. Novel, highly active and stable materials are the fluorinated ormosils. Optimal conditions for the preparation and use thereof in liquid-phase as well as in supercritical COwere set by studying the structure-activity relationships of the materials, with particular reference to the surface hydrophobic/hydrophilic properties and to the textural ones.