The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 18, 2011

Filed:

Dec. 08, 2008
Applicants:

Yun-shan Liu, College Station, TX (US);

Jody Lee Rodgers, Longview, TX (US);

Inventors:

Yun-Shan Liu, College Station, TX (US);

Jody Lee Rodgers, Longview, TX (US);

Assignee:

Eastman Chemical Company, Kingsport, TN (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C07F 9/02 (2006.01); C07C 45/50 (2006.01); B01J 31/00 (2006.01); B01J 27/185 (2006.01);
U.S. Cl.
CPC ...
Abstract

Novel fluorophosphite compounds having the structure of general formula (I): where Arand Arare aryl groups containing 4 to 30 carbon atoms; R1 to R6 are H or alkyl or aryl hydrocarbon radicals containing 1 to 40 carbon atoms; and X is a connecting group or a simple chemical bond, were developed and found to be very active for hydroformylation processes for ethylenically unsaturated substrates. Catalyst solutions prepared from these compounds with a Rh metal show an unusual 'ligand acceleration effect' for simple alkenes, i.e., the hydroformylation activity increases as the concentration of ligand increases, and are capable of producing linear or branched aldehydes under typical hydroformylation conditions.


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