The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 18, 2011

Filed:

May. 15, 2007
Applicants:

Rhonda R. Willigan, Manchester, CT (US);

Thomas Henry Vanderspurt, Glastonbury, CT (US);

Sonia Tulyani, Manchester, CT (US);

Rakesh Radhakrishnan, Vernon, CT (US);

Susanne Marie Opalka, Glastonbury, CT (US);

Sean C. Emerson, Broad Brook, CT (US);

Inventors:

Rhonda R. Willigan, Manchester, CT (US);

Thomas Henry Vanderspurt, Glastonbury, CT (US);

Sonia Tulyani, Manchester, CT (US);

Rakesh Radhakrishnan, Vernon, CT (US);

Susanne Marie Opalka, Glastonbury, CT (US);

Sean C. Emerson, Broad Brook, CT (US);

Assignee:

UTC Power Corporation, South Windsor, CT (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C01B 3/00 (2006.01);
U.S. Cl.
CPC ...
Abstract

A durable catalyst support/catalyst is capable of extended water gas shift operation under conditions of high temperature, pressure, and sulfur levels. The support is a homogeneous, nanocrystalline, mixed metal oxide of at least three metals, the first being cerium, the second being Zr, and/or Hf, and the third importantly being Ti, the three metals comprising at least 80% of the metal constituents of the mixed metal oxide and the Ti being present in a range of 5% to 45% by metals-only atomic percent of the mixed metal oxide. The mixed metal oxide has an average crystallite size less than 6 nm and forms a skeletal structure with pores whose diameters are in the range of 4-9 nm and normally greater than the average crystallite size. The surface area of the skeletal structure per volume of the material of the structure is greater than about 240 m/cm. The method of making and use are also described.


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