The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 07, 2010

Filed:

Aug. 21, 2007
Applicants:

David Cole-hamilton, By St. Andrews, GB;

Simon Laurent Desset, Woluwe-Saint-Pierre, BE;

Inventors:

David Cole-Hamilton, By St. Andrews, GB;

Simon Laurent Desset, Woluwe-Saint-Pierre, BE;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 45/28 (2006.01); C07C 5/03 (2006.01); C09K 3/00 (2006.01);
U.S. Cl.
CPC ...
Abstract

An additive for improving the rate of catalysis in biphasic reaction systems is disclosed. The additive is an ionic molecule comprising an organic cation such as a heterocyclic compound or a quaternary ammonium or phosphonium cation, and an anion which may be organic or inorganic. A process for improved catalysis in an aqueous biphasic system wherein the catalyst is substantially dissolved in the aqueous phase and the substrate is substantially contained in the non-aqueous phase is also described. A suitable additive is 1-octyl-3-methylimidazolium halide. Examples of suitable catalytic reactions include the hydrogenation, hydrosilation, hydroboration, hydrovinylation, hydroformylation, oxidation and hydroxycarbonylation of alkenes, and Heck, Suzuki, Stille, and Sonigashira coupling.


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