The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 16, 2010

Filed:

Oct. 13, 2008
Applicants:

Richard D. Mccullough, Pittsburg, PA (US);

Elena E. Sheina, Pittsburgh, PA (US);

Mihaela C. Iovu, Pittsburgh, PA (US);

Inventors:

Richard D. McCullough, Pittsburg, PA (US);

Elena E. Sheina, Pittsburgh, PA (US);

Mihaela C. Iovu, Pittsburgh, PA (US);

Assignee:

Carnegie Mellon University, Pittsburgh, PA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08G 75/06 (2006.01); C08G 75/00 (2006.01); C08L 81/00 (2006.01);
U.S. Cl.
CPC ...
Abstract

Regioregular poly(3-alkylthiophenes) and other polythiophenes can be prepared by living polymerization which have good solubility, processability and environmental stability. The polymerization method can afford regioregular poly(3-alkylthiophenes) in high yields. Kinetic study of polymerization revealed the living character of this process. The molecular weight of poly(3-alkylthiophenes) is a function of the molar ratio of the monomer to nickel initiator, and conducting polymers with relatively narrow molecular weight distribution (PDI<1.5) are now readily available. Sequential monomer addition resulted in new block copolymers containing different poly(3-alkylthiophene) segments, which further confirms the 'livingness' of this system. Other synthetic methods can be used as well to conduct living polymerization. Blends and electronic devices can be prepared.


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