The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 09, 2010

Filed:

Aug. 04, 2006
Applicants:

Velliyur Nott Mallikarjuna Rao, Wilmington, DE (US);

H. David Rosenfeld, Drumore, PA (US);

Allen Capron Sievert, Elkton, MD (US);

Shekhar Subramoney, Hockessin, DE (US);

Inventors:

Velliyur Nott Mallikarjuna Rao, Wilmington, DE (US);

H. David Rosenfeld, Drumore, PA (US);

Allen Capron Sievert, Elkton, MD (US);

Shekhar Subramoney, Hockessin, DE (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 17/00 (2006.01); C07C 17/10 (2006.01);
U.S. Cl.
CPC ...
Abstract

A process is disclosed for the manufacture of CFCHCHFand CFCHFCHF. The process involves (a) reacting hydrogen fluoride, chlorine, and at least one halopropene of the formula CXCCl═CClX (where each X is independently F or Cl) to produce a product including both CFCClCClFand CFCClFCClF; (b) reacting CFCClCClFand CFCClFCClF produced in (a) with hydrogen to produce a product including both CFCHCHF, and CFCHFCHF; and (c) recovering CFCHCHFand CFCHFCHF from the product produced in (b). In (a), the CFCClCFand CFCClFCClFare produced in the presence of a chlorofluorination catalyst including (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper, and/or (ii) a chromium-containing composition of (i) which has been treated with a fluorinating agent.


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