The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 19, 2010

Filed:

Oct. 25, 2006
Applicants:

Daryle H. Busch, Lawrence, KS (US);

Bala Subramaniam, Lawrence, KS (US);

Hyun-jin Lee, Lawrence, KS (US);

Tie-pan Shi, Ponca City, OK (US);

Inventors:

Daryle H. Busch, Lawrence, KS (US);

Bala Subramaniam, Lawrence, KS (US);

Hyun-Jin Lee, Lawrence, KS (US);

Tie-Pan Shi, Ponca City, OK (US);

Assignee:

University of Kansas, Lawrence, KS (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07D 301/12 (2006.01);
U.S. Cl.
CPC ...
Abstract

A process for the selective oxidation of olefins to epoxides comprising the step of contacting the olefin (propylene) with an oxidant (hydrogen peroxide) in the presence of a Lewis acid oxidation catalyst (MTO), organic base (pyridine or its N-oxide), in a solvent system comprising an organic water-miscible solvent (methanol); and adding a pressurizing gas (nitrogen) to increase the pressure, whereby olefin is further dissolved in organic solvent system to increase the selectivity and yield of the desired epoxide (propylene oxide).


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