The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 10, 2009

Filed:

Aug. 09, 2004
Applicants:

Liping Zhang, Hurricane, WV (US);

Hwaili Soo, Charleston, WV (US);

Juliana G. Serafin, Charleston, WV (US);

Inventors:

Liping Zhang, Hurricane, WV (US);

Hwaili Soo, Charleston, WV (US);

Juliana G. Serafin, Charleston, WV (US);

Assignee:

Dow Global Technologies, Inc., Midland, MI (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07D 301/10 (2006.01);
U.S. Cl.
CPC ...
Abstract

An improved process for the manufacture of ethylene oxide through the epoxidation of ethylene using a catalyst comprising silver and at least one efficiency-enhancing salt of a member of a redox-half reaction pair. Added to the epoxidation reaction is a two-component gas-phase promoter system comprising a chlorine-containing component (for example ethyl chloride, methyl chloride, vinyl chloride and ethylene dichloride), and a nitrogen-containing component of nitric oxide and other compounds capable of generating under reaction conditions at least one gaseous efficiency-enhancing member of a redox-half reaction pair comprising NO, NO, NOor NO. The amount of each component of said gaseous promoter is adjusted to maintain the ration of N* to Z* less than or equal to 1 wherein, N* is the nitric oxide equivalent in ppmv, ranging from 1 to 20 ppmv and Z*=ethyl chloride equivalent (ppmv)*100 percent/ethane equivalent (mol percent)*100 ranging from 5 to 40 ppmv.


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