The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 08, 2009

Filed:

Nov. 16, 2007
Applicants:

Yun-shan Liu, College Station, TX (US);

Thomas Allen Puckette, Longview, TX (US);

Inventors:

Yun-Shan Liu, College Station, TX (US);

Thomas Allen Puckette, Longview, TX (US);

Assignee:

Eastman Chemical Company, Kingsport, TN (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C07C 45/50 (2006.01); B01J 31/00 (2006.01);
U.S. Cl.
CPC ...
Abstract

Disclosed are catalyst solutions for preparing aldehydes with variable normal- to iso-aldehyde ratios comprising one or more phosphonite ligands, rhodium, and a hydroformylation solvent. Also disclosed is a process for preparing aldehydes with variable normal- to iso-aldehyde ratios comprising contacting an olefin, hydrogen, and carbon monoxide with one or more phosphonite ligands, rhodium, and a hydroformylation solvent. The phosphonite-based catalyst solutions provide the ability to manipulate the normal- to iso-aldehyde ratio by varying one or more process variables including carbon monoxide partial pressure, temperature, and gram moles ligand to gram atoms rhodium.


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