The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 07, 2004

Filed:

Jul. 19, 2002
Applicant:
Inventors:

George Alan Vaughan, Houston, TX (US);

John F. Szul, Nitro, WV (US);

Matthew Gary McKee, Blacksburg, VA (US);

James McLeod Farley, League City, TX (US);

Ching-Tai Lue, Houston, TX (US);

Sun-Chueh Kao, Hillsboro, NJ (US);

Assignee:

Univation Technologies, LLC, Houston, TX (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 4/44 ; C08F 4/642 ;
U.S. Cl.
CPC ...
C08F 4/44 ; C08F 4/642 ;
Abstract

The present invention provides polymerization catalyst compounds, catalyst systems including these catalyst compounds, and to their use in the polymerization of ethylene and at least one comonomer. In particular, the invention provides a catalyst system comprising a poor comonomer incorporating catalyst compound and a good comonomer incorporating catalyst compound. Preferably, the low comonomer incorporating catalyst compound is a metallocene containing at least one substituted or unsubstituted fused ring cyclopentadienyl based ligand which is substantially directed to the front of the molecule, contains a long bridging group, or which contains a methyl substitution pattern which correlates to poor comonomer incorporation. The invention also provides methods of selecting the poor comonomer incorporating metallocene to pair with the good comonomer incorporating metallocene to produce polymers that are easy to process into a variety of articles, especially polyethylene based film, having enhanced properties.


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