The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 17, 2004

Filed:

Nov. 20, 2000
Applicant:
Inventors:

Elena H. Too, Branford, CT (US);

Paul R. Gerst, Madison, CT (US);

Vincent Paneccasio, Jr., Madison, CT (US);

Richard W. Hurtubise, Clinton, CT (US);

Assignee:

Enthone Inc., West Haven, CT (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C25D 5/02 ; C25D 1/132 ; C25D 3/38 ; C23C 1/854 ;
U.S. Cl.
CPC ...
C25D 5/02 ; C25D 1/132 ; C25D 3/38 ; C23C 1/854 ;
Abstract

A copper electroplating bath and a method to plate substrates with the bath are provided. The bath and method are particularly effective to plate electronic components such as semiconductive wafer VLSI and ULSI interconnects with void-free fill copper plating for circuitry forming vias and trenches and other small features less than 0.2 microns with high aspect ratios. The copper bath contains a bath soluble organic divalent sulfur compound, and a bath soluble polyether compound such as a block copolymer of polyoxyethylene and polyoxypropylene, a polyoxyethylene or polyoxypropylene derivative of a polyhydric alcohol and a mixed polyoxyethylene and polyoxypropylene derivative of a polyhydric alcohol. A preferred polyether compound is a mixed polyoxyethylene and polyoxypropylene derivative of glycerine. A preferred copper bath also contains a pyridine compound derivative.


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