The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 06, 2004

Filed:

Oct. 15, 2002
Applicant:
Inventors:

Krzysztof Matyjaszewski, Pittsburgh, PA (US);

Jérôme Gromada, Libercourt, FR;

Mei Li, Mars, PA (US);

Assignee:

Carnegie Mellon University, Pittsburgh, PA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 4/42 ;
U.S. Cl.
CPC ...
C08F 4/42 ;
Abstract

The use of concurrent reverse and normal initiation processes in an ATRP enables the use of highly active catalysts under “reverse ATRP” conditions and leads to the synthesis of well-defined polymers with low molecular weight distributions while employing much lower levels of the transition metal in the system. This dual activation/initiating system allows use of active catalysts that are added to the reaction in an oxidatively stable form. The benefits of this dual initiating system can be attained in bulk, solution and multi-phase ATRP processes, including emulsions, miniemulsions and polymerization from surfaces.


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