The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 01, 2004

Filed:

Dec. 18, 2002
Applicant:
Inventors:

John J. Eisch, Vestal, NY (US);

John N. Gitua, Binghamton, NY (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 3/122 ; C08F 4/76 ;
U.S. Cl.
CPC ...
B01J 3/122 ; C08F 4/76 ;
Abstract

A novel family of olefin polymerization catalysts comprising three-membered titanacarbocycles is described and illustrated. The titanacarbocycles can be readily synthesized by utilizing di-n-butyltitanium dichloride or di-t-butyltitanium dichloride at −78° C. in alkane, cycloalkane, or aromatic hydrocarbon media. These catalysts exhibit sufficient stability after their preparation that they undergo a remarkable, unprecedented reaction whereby the titanium dichloride moiety is efficiently transferred to a substrate like diphenylacetylene, ethylene, or similar compounds in order to generate the three-membered titanacarbocycles.


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