The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 03, 2003

Filed:

Jul. 18, 2002
Applicant:
Inventors:

Michael Richard McAtee, Jackson, TX (US);

Rocco Paciello, Bad Dürkheim, DE;

Michael-Dieter Ulbrich, Freinsheim, DE;

Assignee:

BASF Aktiengesellschaft, Ludwigshafen, DE;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 2/720 ; C07C 2/722 ; C07C 2/724 ; C07C 2/915 ; C07C 2/710 ; C07C 2/712 ; C07C 2/714 ; C07C 2/716 ; C07B 2/102 ;
U.S. Cl.
CPC ...
C07C 2/720 ; C07C 2/722 ; C07C 2/724 ; C07C 2/915 ; C07C 2/710 ; C07C 2/712 ; C07C 2/714 ; C07C 2/716 ; C07B 2/102 ;
Abstract

A process for preparing C -alcohols comprises a) providing a C -hydrocarbon stream comprising butene and butane; b) subjecting the C -hydrocarbon stream to oligomerization over an olefin oligomerization catalyst and fractionating the resulting reaction mixture to give an octene-containing stream and a butene-depleted C -hydrocarbon stream; c) subjecting the butene-depleted C -hydrocarbon stream to steam reforming or partial oxidation to give carbon monoxide and hydrogen; d) hydroformylating the octene-containing stream by means of carbon monoxide and hydrogen in the presence of a hydroformylation catalyst to form C -aldehydes, where the carbon monoxide used and/or the hydrogen used originate at least in part from step c); and e) catalytically hydrogenating the C -aldehydes by means of hydrogen. In a variant of the process, part of the butenes present in the C -hydrocarbon stream are hydroformylated to form C -aldehydes, these are subjected to an aldol condensation and the product of the aldol condensation is hydrogenated to form C -alcohols. The process allows the C -hydrocarbon stream used to be substantially utilized as material.


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