The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 13, 2001

Filed:

Sep. 13, 1999
Applicant:
Inventors:

T. Kirk Dougherty, Playa Del Rey, CA (US);

John J. Drab, Santa Barbara, CA (US);

Assignee:

Raytheon Company, Lexington, MA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07F 1/900 ; C07F 7/00 ; C07F 9/00 ; B05D 5/12 ;
U.S. Cl.
CPC ...
C07F 1/900 ; C07F 7/00 ; C07F 9/00 ; B05D 5/12 ;
Abstract

The present invention is directed to the synthesis, processing and test of improved spin-on precursor materials comprising at least one Group II metal and at least one Group IV or Group V metal, useful for making thin oxide films, useful, for example, in various electronic devices, such as ferroelectric devices. For example, barium strontium titanate spin-on precursor materials are useful for making thin films of barium strontium titanate (BST) for, e.g., ferroelectric capacitors. A method is provided for fabricating electronic devices employing such Group II-Group IV (or V) oxides as the active device, using polyether acids. The method comprises: (a) providing a substrate; (b) forming a bottom electrode on the substrate; (c) depositing a solution comprising polyether acid salts of the Group II and Group IV or Group V metal ions; (d) forming the oxide film from the solution; and (e) forming a top electrode on the oxide film. As a consequence of the method, improved electronic devices are formed from less toxic and easier handled precursors and solvents. The present invention provides for a soluble spin-on precursor which is compatible and soluble in non-toxic and environmentally benign solvents. In addition, this spin-on precursor material has been shown to give much improved electrical performance properties of the BST thin films produced.


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