The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 18, 2001

Filed:

Dec. 23, 1998
Applicant:
Inventors:

Nancy W. Eilerts, Bartlesville, OK (US);

Bryan Hauger, Claremore, OK (US);

M. Bruce Welch, Bartlesville, OK (US);

Harold R. Deck, Bartlesville, OK (US);

Assignee:

Phillips Petroleum Company, Bartlesville, OK (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C08F 4/16 ; C08F 4/26 ; C08F 4/44 ;
U.S. Cl.
CPC ...
C08F 4/16 ; C08F 4/26 ; C08F 4/44 ;
Abstract

A process is provided to prepare polyolefins having a multimodal molecular weight distribution comprising contacting at least one mono-1-olefin in a polymerization zone, under polymerization conditions, with a dual catalyst system comprising a first catalyst system which comprises a metallocene catalyst and a cocatalyst and a second catalyst system which comprises diimine nickel complexes which further comprise additional ligands selected from the group consisting of ∝-deprotoned-&bgr;-diketones, ∝-deprotoned-&bgr;-ketoesters, halogens and mixtures thereof. The resultant, recovered polymer has at least a bimodal, or broad, molecular weight distribution.


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