The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 26, 2001

Filed:

Feb. 04, 1999
Applicant:
Inventors:

George A. Blay, Corpus Christi, TX (US);

Ricardo E. Borjas, Corpus Christi, TX (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C25B 3/00 ; C25D 2/106 ; C25D 2/118 ;
U.S. Cl.
CPC ...
C25B 3/00 ; C25D 2/106 ; C25D 2/118 ;
Abstract

A process for electrochemical oxidation of aldehydes to esters is provided. The invention includes electrooxidation at a pH where an intermediate hemiacetal is favored, thereby providing for maximum selectivity to the desired ester and for maximum reaction efficiency. In particular, the invention provides for the electrooxidation of acetaldehyde to methyl acetate. The invention is illustrated with reference reactants native to the carbonylation process for the manufacture of acetic acid. Processes described herein are readily adapted to an industrial scale, particularly for the removal of acetaldehyde from process streams.


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