The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 03, 2000

Filed:

Jul. 23, 1998
Applicant:
Inventors:

Tomasz Sokalski, Warsaw, PL;

Erno Pretsch, Uetikon am See, CH;

Assignee:

Orion Research, Inc., Beverly, MA (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
G01N / ;
U.S. Cl.
CPC ...
204418 ; 204416 ;
Abstract

A new type of ion-selective solvent polymeric or liquid membrane electrode is constructed which allows to extend the measuring range at the lower end by at least six (6) orders of magnitudes. The new method can be used with membranes based on a neutral ionophore, a charged ionophore, or an ion-exchanger. Low detection limits are achieved by maintaining a very low and constant concentration of the primary ion and a sufficiently high concentration of an interfering ion in the internal reference solution. The low and constant concentration of the primary ion is either adjusted with the help of a solution of a hydrophilic ion buffer such as ethylenediamine tetraacetic acid or by adding an excess of a salt of an ion which forms a sparingly soluble salt with the primary ion, such as NaI for the primary ion Ag.sup.+. With the new technique, ion-selective electrodes can be used, for the first time, for environmental monitoring of heavy metal ions such as Pb.sup.2+ and Cd.sup.2+ at the submicromolar level.


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