The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 15, 2000

Filed:

Jul. 07, 1998
Applicant:
Inventors:

David Anthony Schiraldi, Charlotte, NC (US);

Sheldon Christopher Sherman, Alpharetta, GA (US);

Dhiraj Sudesh Sood, Baton Rouge, LA (US);

Mark Gilmore White, Woodstock, GA (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07F / ; C07C / ; B01J / ;
U.S. Cl.
CPC ...
556136 ; 502170 ; 502171 ; 562480 ; 585427 ; 560 96 ;
Abstract

A catalytic process for production of biphenyl and its derivatives by coupling of substituted or unsubstituted monoaryl compounds in the presence of a catalytic system comprising at least one Pd (II) compound and a strong acid or a mixture of acids. The process provides high conversions and high selectivity under mild temperature conditions and short reaction times. The strong acid or mixture of acids has a Hammett acidity of less than about -10, and contains a predominant amount of counterions which form a weak ligand complex with palladium (II). The method is highly selective to formation of desired biaryl isomers, such as 4,4'-isomers, and allows control of the relative amounts of isomers of biaryl compounds and substituted monoaryl compounds in the final product.


Find Patent Forward Citations

Loading…