The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 22, 1999

Filed:

Aug. 22, 1997
Applicant:
Inventors:

Harry R Allcock, State College, PA (US);

Christopher T Morrissey, Fairfield, OH (US);

Ian Manners, Oakville, CA;

Charles H Honeyman, Boston, MA (US);

James M Nelson, Minneapolis, MN (US);

Chester A Crane, State College, PA (US);

Scott D Reeves, State College, PA (US);

A Paul Primrose, University Park, PA (US);

Thomas J Hartle, State College, PA (US);

R Prange, State College, PA (US);

Assignee:

The Penn State Research Foundation, University Park, PA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08G / ;
U.S. Cl.
CPC ...
528399 ; 528 26 ; 528167 ; 528168 ; 528169 ; 528223 ; 528224 ; 528225 ; 528228 ; 528287 ; 528363 ; 528399 ; 525538 ;
Abstract

A process for the preparation of polyphosphazenes is provided that includes the cationic solution polymerization reaction of a phosphoranimine, using a main group or transition metal halide, or other appropriate halide salt, including a linear phosphazene salt of any chain length, or a preformed non-phosphazene polymer containing a main or transition metal chloride, as an initiator. In a preferred embodiment, triarmed-star polyphosphazenes having the formula N{RN(H)R'.sub.2 P--(N.dbd.PR'.sub.2).sub.n }.sub.3 are prepared via this method. Also, a methods for synthesis of the monomer Cl.sub.3 P.dbd.NSiMe.sub.3 and cyclic trimer N.sub.3 P.sub.3 X.sub.6 from the reactants N(SiR.sub.3).sub.3 and PX.sub.5 are also described.


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