The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 25, 1999

Filed:

Aug. 18, 1997
Applicant:
Inventors:

Peter C Foller, Murrysville, PA (US);

David G Roberts, Gibsonia, PA (US);

Robert H Tang, Murrysville, PA (US);

Assignee:

PPG Industries, Inc., Pittsburgh, PA (US);

Attorneys:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C25B / ; C25B / ; C25B / ; C25B / ;
U.S. Cl.
CPC ...
204539 ; 204541 ; 204630 ; 204252 ; 204253 ; 204258 ; 204265 ; 205431 ; 205551 ; 205552 ; 205338 ; 205349 ;
Abstract

Describes a method of electrochemically converting amine hydrohalide, e.g., ethyleneamine hydrochloride, into free amine, e.g., free ethyleneamine. A three compartment electrolytic cell is provided having (1) a catholyte compartment containing a cathode assembly comprising a cathode and an anion exchange membrane, (2) an anode compartment containing an anode assembly comprising either (a) a hydrogen consuming gas diffusion anode and a current collecting electrode or (b) a hydrogen consuming gas diffusion anode which is fixedly held between a hydraulic barrier and a current collecting electrode, and (3) an intermediate compartment separated from the catholyte and anode compartments by the anion exchange membrane and either (i) the hydrogen consuming gas diffusion anode or (ii) the hydraulic barrier respectively. An aqueous solution of amine hydrohalide is charged to the catholyte compartment, while hydrogen gas is charged to the anode compartment and an aqueous conductive electrolyte solution is charged to the intermediate compartment. Direct current is passed through the electrolytic cell and an aqueous solution comprising free amine is removed from the catholyte compartment.


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