The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 15, 1998

Filed:

Jul. 18, 1996
Applicant:
Inventors:

Noboru Sayo, Kanagawa, JP;

Xiaoyong Zhang, Kanagawa, JP;

Tatsuya Omoto, Kanagawa, JP;

Tohru Yokozawa, Kanagawa, JP;

Tetsuro Yamasaki, Kanagawa, JP;

Hidenori Kumobayashi, Kanagawa, JP;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07F / ; C07F / ; C07F / ; C07D / ;
U.S. Cl.
CPC ...
568 10 ; 568 17 ; 546 22 ; 549-5 ; 549-6 ; 549220 ;
Abstract

A novel chiral unsymmetric diphosphine compound of formula (I): ##STR1## wherein Ar.sup.1 and Ar.sup.2, which are different from each other, each represent a substituted or unsubstituted phenyl group, a substituted or unsubstituted naphthyl group, a pyridyl group, a quinolyl group, an isoquinolyl group, a furfuryl group, a benzofurfuryl group, a thienyl group, or a benzothienyl group, and a transition metal complex containing the diphosphine compound as a ligand. The complex catalyzes various asymmetric synthesis reactions, e.g., asymmetric hydrogenation or asymmetric hydrosilylation, exhibiting excellent performance in selectivity, conversion and catalytic activity, to provide a product of desired absolute configuration at high optical purity and in high yield.


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