The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 26, 1998

Filed:

Jan. 10, 1997
Applicant:
Inventors:

Jing-Chemg Tsai, Hsinchu, TW;

Kuang Kai Liu, Hsinchu, TW;

Shu-Ling Peng, Hsinchu, TW;

Shian-Jy Wang, Hsinchu, TW;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F / ; C07F / ;
U.S. Cl.
CPC ...
526127 ; 526126 ; 526131 ; 526132 ; 526133 ; 526134 ; 526153 ; 526159 ; 526161 ; 526346 ; 556-9 ; 556 12 ; 556 40 ; 556 41 ; 502103 ; 502104 ; 502158 ; 502171 ;
Abstract

A novel titanium (III)-based .beta.-diketonate-coordinated compound is disclosed for catalyzing the polymerization reaction of syndiotactic polystyrenes. The titanium (III)-based compound is represented by the following formula 1: ##STR1## wherein X is a C.sub.1 .about.C.sub.12 alkoxy or amine group, or a halogen atom; R is a C.sub.1 .about.C.sub.12 alkyl, aryl, or alkylsilane group. Preferably, X is N(SiMe.sub.3).sub.2 -- or OMe--, and R is phenyl, methyl, or t-butyl. The titanium (III)-based compounds are prepared by reacting titanium trichloride with diketone and tetrahydrofuran to form an intermediate product, then reacting the intermediate product Ti(AcAc)Cl.sub.2 (THF).sub.2 with either aminosilane or alcohol.


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