The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 06, 1998

Filed:

May. 12, 1995
Applicant:
Inventors:

Charles K Buehler, Lansing, MI (US);

Thaddeus W Klimek, Orland Park, IL (US);

Assignee:

Quantum Chemical Corporation, Cincinnati, OH (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C08F / ;
U.S. Cl.
CPC ...
526 60 ; 526 65 ; 526901 ; 526351 ;
Abstract

An improved gas-phase polymerization process for producing in-situ thermoplastic polyolefins in multiple reactors using high activity Ti/Al catalysts is provided. The improvement consists of developing a control parameter derived from eight integrated regions of the copolymer .sup.13 C NMR spectrum, defining the limits of the control parameter for the process, and operating the process to maintain the parameter within the defined limits. This is accomplished by adjusting the amount of ethylene fed to the secondary reactor and adjusting other process variables as required. Thermoplastic polyolefins, i.e., modified polypropylenes, having reduced hexane extractables and improved paint adhesion are also disclosed.


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