The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 09, 1997

Filed:

Jan. 21, 1997
Applicant:
Inventors:

Aref Jallouli, Midland, MI (US);

John Carlton Saam, Midland, MI (US);

Assignee:

Dow Corning Corporation, Midland, MI (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08G / ;
U.S. Cl.
CPC ...
528 21 ; 528 23 ; 528 42 ;
Abstract

Method of making polysiloxanes by ring opening polymerization of 1,3,5-trimethyl-1,3,5-tris(3',3',3'-trifluoropropyl) cyclotrisiloxane (F.sub.3) or 1,3,5,7-tetramethyl-1,3,5,7-tetrakis(3',3',3'-trifluoropropyl) cyclotetras iloxane (F.sub.4) in an acid-free system using electrophillic initiators. The reaction mixture is formed under anhydrous conditions and contains (i) either F.sub.3 or F.sub.4, (ii) a Lewis base such as 2,6-di-tert-butylpyridine which serves as an acid scavenger, and optionally (iii) a salt of a strong acid such as tetrabutylammonium trifluoromethane sulfonate. The anhydrous mixture is contacted with a silyl ester of a strong acid such as triflic acid. The anhydrous reaction mixture is agitated at room temperature until a polysiloxane is formed.


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Jallouli, Aref. (1997). Silyl ester initiators for cyclosiloxane ring opening polymerization (U.S. Patent No. 5696219). U.S. Patent and Trademark Office. https://idiyas.com/patent/badge/5696219

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